Module 02
Thermodynamics from Molecules to Processes
Understand why things happen, not just how to calculate them.
Conceptual Spine
Energy minimizes; entropy maximizes; free energy is the referee.
Lessons
01
The First and Second Laws (Really)
SoonΔU = Q − W; ΔS_universe ≥ 0
02
Enthalpy and When to Use It
SoonH = U + PV
03
Entropy and Spontaneity
SoonDisorder is not the right word
04
Gibbs and Helmholtz Free Energy
SoonG = H − TS
05
Chemical Potential
Soonμi = (∂G/∂ni)_{T,P}
06
Phase Equilibria and the Phase Rule
SoonF = C − P + 2
07
Equations of State
Soonvan der Waals → Peng-Robinson
08
Fugacity and Activity Coefficients
SoonCorrections for real behavior
09
Process Thermodynamics
SoonCycles, efficiency, real systems
Common confusions this module addresses
- ×Chemical potential feels abstract and disconnected from anything physical
- ×Entropy explained as 'disorder' creates wrong intuitions
- ×Not knowing when to use Gibbs vs. Helmholtz
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